柴达木盆地西北缘石英闪长岩的形成时代、岩石成因及地质意义     

辜平阳  陈锐明  查显锋  董增产  庄玉军  查方勇  李培庆 《岩石矿物学杂志》2018,37(1):19-33

柴达木盆地西北缘石英闪长岩Al2O3含量较高,全碱(Alk)含量较低,Na2OK2O,铝饱和指数A/CNK为0.87~0.91,属钙碱性准铝质岩石系列。球粒陨石标准化的稀土元素配分曲线表现为轻稀土元素富集型,轻、重稀土元素分馏明显,Eu弱负异常;微量元素地球化学特征显示,岩石富集Rb、Th、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素,Nb/La和Rb/Nb比值较低,具有I型花岗岩的特征。石英闪长岩Ca O/Na2O比值较高(2.32~2.64),结合源岩判别图解综合推断其源于变玄武岩的部分熔融。全岩Zr饱和温度计算结果显示初始岩浆温度768℃;岩石地球化学特征表明岩浆源区压力1.5 Ga,源岩部分熔融的残留相可能为石榴子石+角闪石+金红石。经过锆石阴极发光分析和MC-LA-ICP-MS锆石U-Pb测年,获得206Pb/238Pb加权平均年龄为252±1 Ma,代表了柴达木盆地西北缘石英闪长岩的成岩年龄。结合区域地质演化特征,认为该岩体形成于与板块俯冲有关的火山弧构造环境,是晚二叠世末期宗务隆洋壳向柴北缘欧龙布鲁克地块俯冲,变玄武岩在相对较高的温压条件下发生部分熔融形成的。  相似文献   

Sugarloaf Mountain,central Arizona,USA: A small-scale example of Miocene basalt-rhyolite magma mixing to yield andesitic magmas     

Ellen J. Craig  R.V. Fodor 《Chemie der Erde / Geochemistry》2018,78(1):116-139

Sugarloaf Mountain is a 200-m high volcanic landform in central Arizona, USA, within the transition from the southern Basin and Range to the Colorado Plateau. It is composed of Miocene alkalic basalt (47.2–49.1?wt.% SiO₂; 6.7–7.7?wt.% MgO) and overlying andesite and dacite lavas (61.4–63.9?wt.% SiO₂; 3.5–4.7?wt.% MgO). Sugarloaf Mountain therefore offers an opportunity to evaluate the origin of andesite magmas with respect to coexisting basalt. Important for evaluating Sugarloaf basalt and andesite (plus dacite) is that the andesites contain basaltic minerals olivine (cores Fo_76-86) and clinopyroxene (～Fs_9-18Wo_35-44) coexisting with Na-plagioclase (An_48-28Or_1.4–7), quartz, amphibole, and minor orthopyroxene, biotite, and sanidine. Noteworthy is that andesite mineral textures include reaction and spongy zones and embayments in and on Na-plagioclase and quartz phenocrysts, where some reacted Na-plagioclases have higher-An mantles, plus some similarly reacted and embayed olivine, clinopyroxene, and amphibole phenocrysts.Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ～61 to 64?wt.% SiO₂ is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77–105 in andesites vs 114–166?ppm in basalts; Zr 149–173 vs 183–237; Nb 21–25 vs 34–42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well ? although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8–16?km and 850° to 980?°C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing ‘collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (～20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.  相似文献   

安徽茶亭铜金矿床赋矿石英闪长玢岩黑云母成分特征及成岩成矿指示意义     

肖庆玲  周涛发  袁峰  王世伟  谢祖军  刘静 《矿床地质》2018,37(6):1179-1194

安徽宣城茶亭矿床位于长江中下游成矿带东南缘的南陵-宣城盆地内,是近年来该盆地内新发现的大型斑岩型Cu-Au矿床。石英闪长玢岩是茶亭矿床主要的赋矿岩石,文章从石英闪长玢岩的造岩矿物黑云母入手,利用EMPA及LA-ICP-MS等原位微区分析方法,对黑云母进行了详细的矿物化学分析,旨在查明赋矿石英闪长玢岩形成的物理化学条件,并探讨其成岩成矿意义。分析结果表明:茶亭赋矿石英闪长玢岩中黑云母具有高w(TiO_2)、低w(Al_2O_3)的特征,整体富Mg、贫Fe。黑云母温压计算结果表明,在不同深度上,石英闪长玢岩具有相似的结晶温度及压力,其结晶温度为746～773℃,压力为44～85 MPa,对应深度为1.7～3.3 km,平均为2.47 km,显示石英闪长玢岩侵位深度相对较浅。黑云母中高的氧化系数(0.613～0.864)、高Mg#(0.557～0.864),以及w(MgO)介于14.73%～15.86%,均显示石英闪长玢岩为壳幔混源,并且以幔源为主。黑云母成分显示石英闪长玢岩形成于较高氧逸度条件下。浅部岩体具有较高的X_(Mg)值,表明浅部岩体氧逸度较高,可能指示随着岩浆的不断演化,残余岩浆的氧逸度不断降低。同时,石英闪长玢岩黑云母相对一般斑岩型铜矿具有较高的w(Cu),并且高Cl、低F。这些特征均有利于茶亭Cu-Au矿床的形成。  相似文献   

估算钙碱性长英质侵入岩结晶压力的地质压力计评述     

徐鸿雪  汪洋 《地质论评》2023,69(4):2023040029-2023040029

本文对四种常见的矿物压力计（角闪石全铝压力计、黑云母压力计、榍石压力计和“石英”压力计）的适用性进行了经验性检验。基于国内外典型钙碱性长英质岩体的矿物化学和全岩化学成分数据,采用不同压力计估算岩体侵位压力,并与角闪石全铝压力计结果对比。结果表明：角闪石六次配位Al压力计与广泛使用的角闪石全铝压力计的估算值存在系统相关性;榍石压力计计算的压力与角闪石全铝压力计的估计结果相关性较为显著;基于Qtz—Ab—Or简并花岗岩体系的“石英”压力计可以用于估计准铝质—弱过铝质钙碱性（狭义）花岗岩的结晶压力。但是,经验性的黑云母压力计和基于实验数据的黑云母压力压计均不能很好地复现角闪石全铝压力计的结果。黑云母压力计不适用于估算钙碱性侵入岩的结晶压力。  相似文献   

江西德兴斑岩铜矿石英闪长玢岩成因及成矿学意义          下载免费PDF全文

鲍波  姜军胜  于玉帅  秦拯纬  郑忠超  柳潇  陕亮  董宜勇  李福林 《岩石矿物学杂志》2023,42(4):483-501

为探究石英闪长玢岩成因及幔源基性岩浆对斑岩铜矿的贡献,本文选取德兴矿床石英闪长玢岩开展了锆石U-Pb定年、Hf同位素和全岩地球化学研究。获得石英闪长玢岩LA-ICP-MS锆石U-Pb年龄为169 Ma,与成矿花岗闪长斑岩侵位时间一致,岩体为中侏罗世岩浆活动的产物。石英闪长玢岩具有低的SiO₂(58.41%~63.12%)和K₂O(1.68%~2.94%)含量及A/CNK值(0.85~1.04),富集大离子亲石元素和轻稀土元素,亏损高场强元素Nb、Ta、Ti和重稀土元素,属于钙碱性到高钾钙碱性系列岩石。具有相对亏损的锆石Hf同位素组成,εHf(t)=2.20~7.93(最大值7.93),指示其源区为岩石圈地幔。锆石稀土元素配分模式图显示出明显的正Ce异常,岩浆氧逸度(lg f_O2)为-20.05~-6.66,达到磁铁矿-赤铁矿氧逸度等级,指示石英闪长玢岩结晶自高氧逸度岩浆。全岩地球化学特征显示,德兴石英闪长玢岩与成矿花岗闪长斑岩及其暗色包体符合岩浆混合的演化趋势,说明成矿花岗闪长斑岩可能是中侏罗世幔源基性岩浆和地壳酸性岩浆大规模混合作用的产物,并且石英闪长玢岩代表了岩浆混合过程中的幔源基性端员。结合前人研究成果,认为在中侏罗世伸展构造背景下,软流圈物质上涌导致新元古代受交代的岩石圈地幔部分熔融形成幔源基性岩浆,基性岩浆的底侵作用诱发下地壳物质熔融并与之发生一定程度的岩浆混合作用,形成了花岗闪长斑岩的母岩浆。高氧逸度幔源岩浆的加入可抑制斑岩体系硫化物的过早饱和,同时为德兴矿床注入了成矿所需的部分挥发分和金属元素。  相似文献   

鄂东南付家山脉石英矿杂质特征及其用作高纯石英原料的潜力     

谢泽丰  王九一  彭琰聪  胡宇飞 《岩石矿物学杂志》2022,41(6):1159-1168

作为战略性矿产资源之一,高纯石英已广泛应用于集成电路、半导体芯片、太阳能等高新技术产业中,但是能够生产高纯石英的原料矿床极为稀缺,我国尤为紧缺高纯石英原料矿。鄂东南地区是湖北省脉石英矿床的主要分布区。本文针对鄂东南付家山脉石英矿床,通过光学显微镜、扫描电子显微镜观察了脉石英的脉石矿物类型和包裹体特征,采用电感耦合等离子发射光谱法(ICP-OES)对原矿进行了微量元素分析,旨在获得付家山脉石英矿床的杂质元素特征,进而评价矿床用作高纯石英原料的潜力。结果表明,付家山脉石英矿石SiO₂含量大于99.95%,杂质元素主要为Al、K、Fe、Ti、Ca等,脉石矿物主要有白云母、钾长石、铁氧化物等,流体包裹体较为发育。杂质元素分析结果表明,付家山脉石英原矿质量达到低端高纯石英标准,经传统工艺提纯后,可能具有生产中高端高纯石英的潜力。  相似文献   

The Role of Seal and Source Rocks in Fluid-rock Interactions and their Reservoir Effects within the Carbonate Deep Burial Realm     

LI Jie  CAI Zhongxian 《《地质学报》英文版》2022,96(4):1353-1361

Discoveries of deep high-quality carbonate reservoirs challenged the general understanding on the evolution of porosity decreasing with depth. New mechanisms of pore generation and preservation in the deep realm require to be proposed. Dolostones in the Feixianguan and Dengying Formations experienced maximum depths in excess of 8000 m, but still retained high porosity. Petrographic observation and homogenization temperatures help to identify products of deep fluid-rock interactions, visual and experimental porosity were used to quantify reservoir effects, the distribution of products finally being plotted to unravel the mechanisms. Th data reveal that thermochemical sulfate reduction (TSR), burial dissolution and quartz cementation are typical deep fluid-rock interactions. The SO42? of residual porewater sourced from the evaporative dolomitizing fluid was supplied for TSR in the hydrocarbon column, the TSR-inducing calcite cements were homogeneously dispersed in the hydrocarbon column. Quartz cementation was caused by the increasing acidity and Si-rich residual porewater in the oil column. Burial dissolution is forced by organic acid and limited in oil–water contact. This study suggests that seal and source rocks not only play important roles in hydrocarbon accumulation, but also have a general control on the deep fluid-rock interactions and porosity evolution in the deep burial realm.  相似文献   

河北金厂峪金矿床辉钼矿与金矿化关系研究及意义     

孙豪  宋扬  李超  郑明  孙鹏程  方颖 《地球学报》2022,43(2):157-171

辉钼矿Re-Os测年方法现已广泛应用于各类金属硫化物矿床成矿年代学研究领域, 已成为石英脉型金矿床实现直接、准确定年的重要手段。然而, 正确理解辉钼矿与金成矿作用之间的确切关系, 选取具有代表性的辉钼矿样品是测年的前提。本文聚焦冀东地区规模最大的金矿床——金厂峪金矿床, 对其石英-钠长石-多金属硫化物脉中的黄铁矿和辉钼矿两者的产出状态及原位微量元素特征进行了详尽的对比, 研究探讨了金厂峪金矿床中辉钼矿与金矿化之间的关系。研究发现石英-钠长石-多金属硫化物脉含金丰富, 可见金和不可见金均大量赋存, 黄铁矿和辉钼矿均为重要的载金硫化物。镜下矿相学及原位微量元素证据表明, 早期形成的含金黄铁矿经历了再活化过程, 为稍晚形成的富金辉钼矿提供了大量的Au源, 两者可能为同一大的金成矿事件下不同成矿流体脉冲事件的产物。辉钼矿形成于金厂峪金矿的主成矿阶段, 与Au的二次浓集紧密相关, 并可作为高品位金矿体的标志性矿物之一。本文认为在准确厘定辉钼矿与金矿化关系的基础上, 辉钼矿Re-Os方法是一种可靠的石英脉型金矿直接定年手段。  相似文献   

肃北钻井沟金矿的矿石特征和金的赋存状态探讨          下载免费PDF全文

李作军  惠剑宁  杨发旺  梁军  魏学平 《甘肃地质》2012,(2):54-56

钻井沟金矿主要的矿石类型为含金多金属硫化物石英脉和含金白云母石英岩,矿石结构以粒状晶结构、碎裂结构和包含结构为主;构造主要为块状构造和浸染状构造。金矿物为自然金,以裂隙金为主,少量包裹金,金矿物以中粗粒金为主,载金矿物为黄铁矿、黄铜矿和石英。矿石中金的品位高,赋存状态简单,有害元素砷、锑、硫、碳等的含量低,属易浸型矿石。采用浮选—氰化联合工艺流程,金的综合回收率可以到达99.24%。  相似文献   

中国庐山晚第四纪沉积岩系的石英形貌显微结构及环境过程     

胡东生  李小豫  熊卫强  张华京  弓虎军  胡文瑄  张国伟 《地质学报》2012,86(6):1020-1030

基于庐山山地晚第四纪地层典型断面的系统调查,从地层剖面层序中筛选的微粒(θ=1～3mm)石英颗粒进行环境电子显微镜观测研究,辨认出显微结构-颗粒形态-变形构造-动力化学作用等特征,运用系统过程发展中的节点事件进行层型剖面的环境响应分析,采取综合指标表征地球表层过程及环境响应情景,明确划分出四个古气候环境发展阶段,由下往上分别表现为冰期环境-间冰期环境-冰缘环境-冰后期环境,为深入研究及科学认识庐山第四纪环境演化过程及全球变化提供了新的基础依据。  相似文献